Stress corrosion cracking susceptibility of medium carbon. Stress corrosion cracking scc of austenitic 304 stainless steel in chloride environment is a common problem in industries. Corrosion is related to the susceptibility of the material to the environment, while. A corrosive medium especially chloridebearing or hydrogensulphide h 2 s media. Stress corrosion cracking of 304l stainless steel and 1 14 cr 12. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. Though potassium hydroxide is slightly more aggressive, this generally relates to its higher boiling point and the increased likelihood of highertemperature exposure. The stress corrosion cracking scc behaviour of medium carbon steel mcs in caustic soda, potash and a mixture of these reagents was. Stress corrosion cracking behavior of nickel base alloys. To prevent erosioncorrosion, one may change the water chemistry or reduce the velocity of the water, or both. It is a form of stress corrosion cracking characterized by surface initiated cracks.
Stress corrosion cracking scc is characterized by cracks propagating either transgranularly or intergranularly along grain boundaries. This type of failure is known as stress corrosion cracking, often abbreviated to scc. From the chemical composition point of view, corrosion resistant nickel based alloys are categorized as pure nickel, nickelcopper alloys, nickelmolybdenum alloys, nicrmo alloys and nicrfemo alloys. Corrosion by caustic sodium or potassium hydroxide at all concentrations is easily handled at room temperature with a variety of metals and alloys, including carbon steels. The stress corrosion cracking scc behaviour of medium carbon steel mcs in caustic soda, potash and a mixture of these reagents was studied by fracturing this material on a tensometer after every seven days of immersion in these media. Ricker, national institute of standards and technology stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Selection of stainless steels for handling sodium hydroxide. In corrosion behavior and safety requirements, potassium hydroxide is very similar to sodium hydroxide naoh. The resistance of metals to stress corrosion cracking is always less when tension is applied in a transverse direction. Borode school of chemical and metallurgical engineering, faculty of engineering and the built. Potassium hydroxide koh stress corrosion cracking scc caused failure of a type 304l uns s30403 stainless steel bypass in a steam.
It becomes increasingly more corrosive with increasing temperature and concentration. Nickel alloys resistance performance in alkali media. The stress corrosion cracking scc behaviour of medium carbon steel mcs in caustic soda, potash and a mixture of these reagents was studied by. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Caustic stress corrosion cracking inspectioneering. Stress corrosion cracking scc is a fracture process that involves the combined and simultaneous action of a tensile stress and a corrosive environment. Stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Stress corrosion cracking scc or called as environmentally assisted cracking eac may take place at the electrochemical potential range. The original 1997 cepa stress corrosion cracking recommended practices hereafter referred to as the practices were prepared and made public by cepa in response to a the national energy board of canadas public inquiry mh295 into the problem of stress corrosion cracking scc in oil and gas pipelines. Alloy 400 n04400 and alloy 600 n06600 also have excellent stress corrosion resistance. Industrial experience on the caustic cracking of stainless.
Caustic stress corrosion cracking, also referred to as caustic embrittlement, is a form of degradation that is caused when a component operates in a caustic environment. Caustic cracking from potassium hydroxide in syngas journal. This damage mechanism primarily affects standard and high carbon stainless steels, but low carbon and chemically stabilized stainless steels may also be vulnerable under certain. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. Stress corrosion cracking caustic embrittlement of super. There are several types of stress corrosion cracking scc, for example, chlorideinduced scc and h 2 sinduced scc. Stress corrosion cracking of stainless steels in high. Your tanks are the core of your brewery, so it is important to understand what scc is, what causes it, and what to do when your tanks suffer from this type of damage. For the susceptibility to stress corrosion cracking, the directional variation can be appreciable and must be considered in the design of the fabricated hardware.
In many ways, caustic scc of stainless steel represents a forgotten phenomenon, since it was researched, studied and quantified in the 60s and 70s. For the elevated temperature caustic applications that include sulfur, inconel alloy 600 is recommended over nickel alloy 201. Stress corrosion cracking is the cracking of a susceptible metal under the mixed influence of a tensile stress either residual or applied in a corrosive environment 46. To prevent erosion corrosion, one may change the water chemistry or reduce the velocity of the water, or both. For the water chemistry, the ph must be below 9, and the carbonate and the silica levels must be reduced. As with other cracking mechanisms, there is a threshold stress level where cracking will not occur. Caustic stress corrosion cracking how is caustic stress. The stress corrosion cracking scc behaviour of medium carbon steel mcs in caustic soda, potash and a mixture of these reagents was studied by fracturing this material on a tensometer after. Mild steels steels with low carbon and low alloy content and. Carbon cracking caused intergranular scc in both media due to retained internal stresses in the steel while hydrogen cracking also occurred in caustic soda.
Stress corrosion cracking in aluminum alloys is characteristically intergranular. Abstract the paper discusses stress corrosion cracking scc of stainless steel components due to the ingress of caustic into steam systems. Stress corrosion cracking international institute of. Crack propagation can increase dramatically with temperature and can grow through the wall in a matter of hours during temperature excursions especially in conditions that promote caustic concentration. Stress corrosion cracking studies of b, b2 and b3 alloys in acidic solutions were carried out under laboratory and plant conditions nakahara and shoji 1996. Caustic cracking is a form of stress corrosion cracking most frequently encountered in carbon steels or ironchromiumnickel alloys that are exposed to concentrated hydroxide solutions at temperatures of 482f 250c. Abstract commercially pure nickel n02200, its lower carbon version n02201 and various nickel base alloys and stainless steels have been used extensively in many chemical processes and other applications where resistance to a multitude of different. The required tensile stresses may be in the form of directly applied stresses or in the form of residual.
Stress corrosion cracking this refers to the cracking caused by the simultaneous presence of tensile stress and a specific corrosive medium. Caustic stress corrosion cracking caustic embrittlement. Stress corrosion cracking of steel and aluminum in sodium. All the above mentioned findings confirm that the cracking of boiler tubes was mainly by caustic embrittlement owing to the high concentration of caustic soda. Stress corrosion cracking scc stress corrosion cracking scc is the bane of aluminum alloys. In the hydroiodic acid at temperatures exceeding 177oc, alloy b2 was sensitive to transgranular stress corrosion cracking. According to the electrochemical theory, this requires a condition along grain boundaries that makes them anodic to the rest of the microstructure so that corrosion propagates selectively along them.
Thus, the addition of caustic soda to boiler feed waters to reduce the corrosiveness of the latter towards mild steel can result in the form of stress corrosion frequently referred to as caustic cracking. The potassium hydroxide environment required higher temperatures to crack the. It is likely that the cracking sensitivity of ni alloys is related to deallloying mechanism. Scope this article identifies what i would like to know about stress corrosion cracking and. Stress corrosion cracking of stainless steel components in.
It is one of the most prevalent afflictions in the industry and one of many environmental cracking mechanisms that typically occur in carbon steel equipment, but it can also. Stress corrosion cracking in a brewery paul mueller company. It occurs in piping and equipment exposed to caustic, primarily adjacent to non pwht welds. Alloy b2 is damaged by intergranular stress corrosion cracking in the heat affected region when subjected to organic solvents comprising of sulfuric acid at 120oc.
Materials science and engineering, 25 1976 207 215 207 elsevier sequoia s. Stress corrosion cracking scc is a type of environmentallyassisted cracking eac, or the formation of cracks caused by various factors combined with the environment surrounding the pipeline. Carryover of caustic soda naoh in the steam path caused. Chromium induces passivation in oxidizing acids, as it does in the stainless steels. In addition, the literature on stress corrosion cracking of stainless steels. For caustic stress corrosion cracking, what is the effect of temperature and concentration mechanisms. Stress corrosion cracking susceptibility of medium carbon steel in. Sep 18, 2017 fracture mechanicsbased testing was used to quantify the stress corrosion cracking and corrosion fatigue behavior of a precipitationhardened martensitic stainless steel custom 465h950 in full. What causes stress corrosion cracking in pipelines. Staehle the ohio state university, department of metallurgical engineering, columbus, ohio 43210 u. Stress corrosion cracking industrial metallurgists.
This due to high concentration of the caustic soda added to the boiler water to control ph ph 9. Scc occurs when the tensile stress and a specific environment are able to cause failure by their combined action, but are insufficient to cause failure by either one acting alone. Aug 01, 2018 caustic cracking is a form of stress corrosion cracking most frequently encountered in carbon steels or ironchromiumnickel alloys that are exposed to concentrated hydroxide solutions at temperatures of 482f 250c. Polythionic acid stress corrosion cracking pascc is a type of intergranular stress corrosion that affects sensitized stainless steels in refineries processing feedstocks containing sulphur. Pdf stress corrosion cracking scc of nickelbased alloys. During this type of cracking, the metal is virtually unattacked over most of the surface while fine cracks progress through it at the attack site. Stress corrosion cracking scc can slowly destroy your brewery equipment without warning. Nicrmo alloys the nicrmo alloys are particularly resistant to the insidious and unpredictable forms of corrosion caused by chlorides. Although, alloy 600 can get stress corrosion cracking in some alkali conditions. The interaction of corrosion fatigue and stresscorrosion.
Corrosion resistance of nici corrosion resistance of nickel alloys in caustic solutions. Scc occurs as a result of a combination between corrosion and tensile stress. Caustic stress corrosion cracking occurs at higher temperatures than chloride stress corrosion cracking. The area of risk in sodium hydroxide is shown on the iso corrosion diagram by the area bounded by a green line. Aexcellent potassium nitrate bgood potassium oxalate bgood potassium permanganate bgood potassium sulfate bgood 304 stainless steel corrosion compatibility chart. Stainless steels are more resistant to general corrosion compared with carbon steel.
Nickel alloys are less sensitive to stress cracking in potassium. Susceptibility to caustic scc is dependent on several variables, including alloy content, caustic concentration, temperature and stress level. Further tests are needed to define the optimum weld procedure. Corrosion resistance of nici caustic potash in free thesaurus. Environments that may cause stress corrosion cracking in nickel alloys include hot caustic solutions, high temperature water and hot and wet hydrofluoric acid. Despite the extensive qualification of inconel for specific applications, a number of corrosion problems have arisen with inconel tubing. Caustic potash definition of caustic potash by the free.
This damage mechanism primarily affects standard and high carbon stainless steels, but low carbon and chemically stabilized stainless steels may also be. The important general point is that those environments that cause stress corrosion are frequently highly specific to the particular. For the susceptibility to stresscorrosion cracking, the directional variation can be appreciable and must be considered in the design of the fabricated hardware. It is one of the most prevalent afflictions in the industry and one of many environmental cracking mechanisms that typically occur in carbon steel equipment, but it can also afflict low alloy and austenitic. The useful safe limit of carbon steel is approximately 150 o f65 o c, both with regard to caustic stress corrosion cracking cscc and corrosion. Highperformance alloys for resistance to aqueous corrosion. Nesic, erosioncorrosion of mild steel in hot caustic. The area of risk in sodium hydroxide is shown on the isocorrosion diagram by the area bounded by a green line. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment.
Potassium hydroxide these corrosion data are mainly based on results of general corrosion laboratory tests, carried out with pure chemicals and water solutions nearly saturated with air the corrosion rate can be quite different if the solution is free from oxygen. Stress corrosion cracking and corrosion fatigue sciencedirect. Risk of stress corrosion cracking attack caustic stress corrosion cracking occurs at higher temperatures than chloride stress corrosion cracking which can occur at temperatures as low as 60 degc. Pdf caustic soda is used in several refinery processes. It is a form of stress corrosion cracking characterized by sur which materials are susceptible to caus carbon, low alloy steels and 300ss are susceptible. Potassium hydroxide caustic potash bgood potassium hypochlorite cfair potassium iodide. Borode, stress corrosion cracking susceptibility of medium carbon steel in caustic and potash media, australian journal of technology, vol. Stress corrosion cracking scc of nickelbased alloys. Improved resistance to caustic stress corrosion cracking can be given to inconel by heat treating it at 620 o c to 705 o c, depending upon prior solution treating temperature. Citeseerx document details isaac councill, lee giles, pradeep teregowda. It is the least for the short transverse direction. Corrosion resistant alloy an overview sciencedirect topics. Stress corrosion cracking scc is the formation and growth of crack through. Scope this article identifies what i would like to know about stress corrosion cracking and includes corrosion.
Specialized corrosion doehdbk1015193 corrosion ch02 rev. Therefore, alloy 600 components should be stress relieved before using and operating stresses should be used to a minimum. It has also been reported that b2 alloy was prone to transgranular stress corrosion cracking in the presence of hydroiodic acid hi above 177c. Stress corrosion cracking the international institute of. These alloys can however suffer from caustic stress corrosion cracking at caustic concentrations above 70% at temperatures above 290crmo c 550f.